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Carbon nanotube chemistry : ウィキペディア英語版
Carbon nanotube chemistry
Carbon nanotube chemistry involves chemical reactions, which are used to modify the properties of carbon nanotubes (CNTs). CNTs can be functionalized to attain desired properties that can be used in a wide variety of applications. The two main methods of CNT functionalization are covalent and non-covalent modifications.
Because of their hydrophobic nature, CNTs tend to agglomerate hindering their dispersion is solvents or viscous polymer melts. The resulting nanotube bundles or aggregates reduce the mechanical performance of the final composite. The surface of CNTs can be modified to reduce the hydrophobicity and improve interfacial adhesion to a bulk polymer through chemical attachment.
== Covalent modification ==

Covalent modification attaches a functional group onto the carbon nanotube. The functional groups can be attached onto the side wall or ends of the carbon nanotube.〔 The end caps of the carbon nanotubes have the highest reactivity
due to its higher pyrimidization angle and the walls of the carbon nanotubes have lower pyrimidization angles which has lower reactivity. Although covalent modifications are very stable, the bonding process disrupts the sp2
hybridization of the carbon atoms because a σ-bond is formed.〔 The disruption of the
extended sp2 hybridization typically decreases the conductance of the carbon nanotubes.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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